Browsing by Author "Molander, Gary A."
Now showing items 1-3 of 3
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Copper-mediated N-arylation of methyl 2-aminothiophene-3-carboxylate with organoboron reagents
Rizwan, Komal; Karakaya, İdris; Heitz, Drew; Zubair, Muhammad; Rasool, Nasir; Molander, Gary A. (PERGAMON-ELSEVIER SCIENCE LTD,, 2015)A practical protocol for the synthesis of N-arylated methyl 2-aminothiophene-3-carboxylate has been developed via Chan Lam cross-coupling. The desired products were synthesized by cross-coupling of methyl 2-aminothiophen ... -
Photoredox cross-coupling: Ir/NidDual catalysis for the synthesis of Benzylic Ethers
Karakaya, İdris; Primer, David N.; Molander, Gary A. (AMER CHEMICAL SOC., 2015)Single-electron transmetalation has emerged as an enabling paradigm for the cross-coupling of C-sp(3) hybridized organotrifluoroborates. Cross-coupling of alpha-alkoxymethyl-trifluoroborates with aryl and heteroaryl bromides ... -
Single-electron transmetalation: An enabling technology for secondary alkylboron cross-coupling
Primer, David N.; Karakaya, İdris; Tellis, John C.; Molander, Gary A. (AMER CHEMICAL SOC, 2015)Single-electron-mediated alkyl transfer affords a novel mechanism for transmetalation, enabling cross-coupling under mild conditions. Here, general conditions are reported for cross-coupling of secondary alkyltrifluoroborates ...